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1 entry selected.
CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=99718 Help
TitleFurther crystallographic confirmation that Cs(+) ions can occupy sodalite cavities and double six-rings. Crystal structure of fully dehydrated partially Cs(+)-exchanged zeolite X, (Cs45 Na47) (Si100 Al92 O384) - FAU.
AuthorsRyu Kum Sook; Bae Myung Nam; Kim Yang; Seff, K.
ReferenceMicroporous and Mesoporous Materials (2004) 71, 65-75
Link XRef SCOPUS Google
CompoundAl92 Cs45.3 Na46.7 O384 Si100 - [Zeolite X] Caesium sodium tecto-alumosilicate * [A44B49C92D100X384] [cF668] [g9 f e4 c] []
Cell24.898(10), 24.898(10), 24.898(10), 90, 90, 90
FD3-Z (203) V=15434.53
RemarksR=0.066000 : M =Zeolite X : T =294 : D
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
Si1(96g)4
Al1(96g)3
Si2(96g)4
O1(96g)-2
O2(96g)-2
O3(96g)-2
O4(96g)-2
Na1(16c)1
Na2(32e)1
Na3(96g)1
Cs1(16c)1
Cs2(32e)1
Cs3(32e)1
Cs4(32e)1
Cs5(48f)1
Cs6(96g)1
-0.00.120.0301
-0.00.030.1200.95
-0.00.120.0300.04
0.880.000.1001
-0.0-0.00.1401
-0.00.060.0601
-0.00.080.1701
0.0.0.0.010.88
0.220.220.2200.84
0.400.050.120.030.05
0.0.0.0.010.11
0.090.090.0900.06
0.160.160.1600.15
0.260.260.2600.15
0.420.120.1200.62
0.450.070.070.130.01
Atom (site) Oxid. U11, U22, U33, U12, U13, U23
Si1(96g)4
Al1(96g)3
Si2(96g)4
O1(96g)-2
O2(96g)-2
O3(96g)-2
O4(96g)-2
Na1(16c)1
Na2(32e)1
Na3(96g)1
Cs1(16c)1
Cs2(32e)1
Cs3(32e)1
Cs4(32e)1
Cs5(48f)1
Cs6(96g)1
.014.015.009-.00-.00-.00
.011.010.010-.00-.00-.00
.011.010.010-.00-.00-.00
.024.040.025-.00.002-.00
.019.027.011.004-.00-.01
.027.015.019.011.005.000
.013.019.025-.00-.00-.00
000000
.066.066.066.046.046.046
000000
000000
.071.071.071-.02-.02-.02
.071.071.071-.00-.00-.00
.029.029.029.000.000.000
.024.085.0930.0.-.01
000000

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