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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=63379 Help
TitleInsertion of carbon disulphide into a metal-chlorine bond; X-ray structure of Au Cl2 (hapto2-S2 C Cl).
AuthorsJentsch, D.; Jones, P.G.; Thoene, C.; Schwarzmann, E.
ReferenceIC&volume=1989&fpage=149&details=yes target=icsd_help>Journal of the Chemical Society. Chemica (1989) 1989, 149-149
Link XRef SCOPUS Google
CompoundC1 Au1 Cl3 S2 - Dichloro(hapto2-dithiochloroformate)gold(III) [ABX2Y3] [mS56] [f7] []
Cell14.895(5), 10.325(3), 10.765(3), 90., 120.19(2), 90.
C12/C1 (15) V=1431.
RemarksR=0.050000 : P =78-2169 :
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.
PDF 78-2169
Cell in I12/c1-setting: a'=13.284, beta'=104.27

Atom (site) Oxid. x, y, z, B, Occupancy
Au1(8f)3
Cl1(8f)-1
Cl2(8f)-1
Cl3(8f)-1
S1(8f)-2
S2(8f)-2
C1(8f)4
0.330.620.4601
0.150.610.3201
0.340.450.6101
0.560.860.4401
0.340.790.3301
0.500.650.5701
0.470.770.4401
Atom (site) Oxid. U11, U22, U33, U12, U13, U23
Au1(8f)3
Cl1(8f)-1
Cl2(8f)-1
Cl3(8f)-1
S1(8f)-2
S2(8f)-2
C1(8f)4
0.060.030.06-.000.04-.00
0.060.060.06-.010.030.00
0.070.060.11-.000.050.03
0.090.080.09-.050.07-.02
0.090.050.06-.010.05-.00
0.060.060.08-.010.040.00
0.050.050.06-.010.04-.01

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