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1 entry selected.
CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=202105 Help
TitleAxial-ligand and metal-metal trans influences in binuclear platinum(III) complexes. Crystal structures and spectroscopic properties of K4 Pt2 (P2 O5 H2)4 (S C N)2 (H2 O)2 etc..
AuthorsChe, C.M.;Lee, W.M.;Mak, T.C.W.;Gray, H.B.
ReferenceIC&volume=108&fpage=444&details=yes target=icsd_help>Journal of the American Chemical Society (1986) 108, 444-445
Link XRef SCOPUS Google
CompoundH12 K6 N4 O30 P8 Pt2 - Hexapotassium bis(nitro)di-mue-dihydrogendiphosphato(III)-duo-diplatin te(III) dihydrate [A4B7C12D16X58] [mS242] [f26 e2] []
Cell16.545(3), 18.091(7), 10.653(2), 90., 92.8, 90.
C12/C1 (15) V=3184.8
RemarksR=0.035000 : D
Deviation of the charge sum from zero tolerable.
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.
Difference between the formula calculated from the PARM record and the FORM record tolerable.

Atom (site) Oxid. x, y, z, B, Occupancy
Pt1(8f)3
P1(8f)3
P2(8f)3
P3(8f)3
P4(8f)3
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(8f)-2
O6(8f)-2
O7(8f)-2
O8(8f)-2
O9(8f)-2
O10(8f)-2
N1(8f)3
O11(8f)-2
O12(8f)-2
K1(8f)1
K2(4e)1
K3(4e)1
K4(8f)1
O13(8f)-2
O14(8f)-2
N2(8f)3
O15(8f)-2
N3(8f)3
O16(8f)-2
N4(8f)3
O17(8f)-2
N5(8f)3
O18(8f)-2
N6(8f)3
H1(8f)1
0.300.20-.0501
0.200.11-.1001
0.080.200.0101
0.330.140.1301
0.210.220.2501
0.120.12-.0101
0.220.03-.0901
0.150.13-.2301
0.020.22-.0901
0.040.190.1301.
0.260.140.2201
0.350.060.1201
0.400.170.2101
0.140.200.3101
0.270.260.3401
0.380.13-.1501
0.450.12-.1001
0.370.10-.2501
-.100.30-.0001
0.50.010.2501
0-.100.2501
0.20-.000.1401
0.620.040.0601.
0.110.070.440.080.54
0.110.070.440.080.27
0.030.040.220.150.36
0.030.040.220.150.18
0.03-.000.080.090.26
0.03-.000.080.090.13
0.090.090.480.070.18
0.090.090.480.070.09
0.100.050.340.090.16
0.100.050.340.090.08
06.
Atom (site) Oxid. U11, U22, U33, U12, U13, U23
Pt1(8f)3
P1(8f)3
P2(8f)3
P3(8f)3
P4(8f)3
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(8f)-2
O6(8f)-2
O7(8f)-2
O8(8f)-2
O9(8f)-2
O10(8f)-2
N1(8f)3
O11(8f)-2
O12(8f)-2
K1(8f)1
K2(4e)1
K3(4e)1
K4(8f)1
O13(8f)-2
O14(8f)-2
N2(8f)3
O15(8f)-2
N3(8f)3
O16(8f)-2
N4(8f)3
O17(8f)-2
N5(8f)3
O18(8f)-2
N6(8f)3
H1(8f)1
0.010.010.010.000.00-.00
0.020.010.02-.000.00-.00
0.010.020.02-.000.00-.00
0.020.020.020.00-.000.00
0.020.020.010.000.000.00
0.020.020.02-.000.00-.00
0.030.020.030.000.00-.00
0.030.030.02-.00-.00-.00
0.020.030.03-.00-.00-.00
0.020.040.03-.010.01-.00
0.020.020.020.000.000.00
0.040.020.030.000.000.00
0.020.050.02-.00-.000.00
0.030.030.020.000.010.00
0.040.030.02-.00-.000.00
0.020.020.030.000.00-.00
0.020.040.050.000.00-.01
0.040.040.030.000.00-.01
0.030.030.03-.000.000.00
0.030.040.0500.000
0.030.040.090-.020
0.140.120.06-.09-.030.05
0.050.040.040.01-.00-.00
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000

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