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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=84709
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Title
Synthesis, crystal structure, and magnetic properties of a new polymorphic sodium cobalt phosphate with trigonal bipyramidal Co(2+) and a tunnel structure.
Authors
Feng, P.-Y.;Bu, X.-H.;Stucky, G.D.
Reference
IC&volume=129&fpage=328&details=yes target=icsd_help>Journal of Solid State Chemistry (1997)
129
, 328-333
Link
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Compound
Co1 Na1 O4 P1
- Sodium tecto-cobalto(II)phosphate(V)
[
ABCX4
] [
mP56
] [
e14
] [
]
Cell
5.7856(1), 11.0954(2), 9.9228(3), 90., 92.668(2), 90.
P121/C1 (14)
V=636.29
Remarks
R=0.021000 :
Atom (site) Oxid.
x, y, z, B, Occupancy
Co1
(4e)
2
Co2
(4e)
2
P1
(4e)
5
P2
(4e)
5
Na1
(4e)
1
Na2
(4e)
1
O1
(4e)
-2
O2
(4e)
-2
O3
(4e)
-2
O4
(4e)
-2
O5
(4e)
-2
O6
(4e)
-2
O7
(4e)
-2
O8
(4e)
-2
0.88
0.10
0.26
0.00
1
0.65
0.87
0.50
0.00
1
0.62
0.61
0.32
0.00
1
0.12
0.86
0.41
0.00
1
0.87
0.63
0.62
0.02
1
0.37
0.65
0.63
0.01
1
-.09
0.93
0.37
0.00
1
0.59
0.03
0.17
0.01
1
0.15
0.03
0.15
0.01
1
0.15
0.77
0.30
0.01
1
-.08
0.19
0.44
0.01
1
0.34
0.94
0.42
0.00
1
0.61
0.70
0.44
0.01
1
0.63
0.81
0.69
0.01
1
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